Holly Willoughby, Geri Horner, Rod Stewart and Penny Lancaster pose for VERY star-studded snap

Holly Willoughby led the glamour as she attended a Prince’s Trust event at Kensington Palace alongside Geri Horner and Rod Stewart on Thursday.

The This Morning presenter and Prince’s Trust patron, 39, looked incredible in a black and pink off-the-shoulder gown as she posed with Geri, 47, her husband Christian Horner, 47, rocker Rod, 75, his wife Penny Lancaster, 48, Holly’s husband Dan Baldwin, 45, and Ronnie Wood’s wife Sally, 42.

Holly finished her look by styling her signature blonde locks into a glamorous blow-dried hairdo, she added a slick of make-up to enhance her pretty features.

Star-studded: (L-R) Rod Stewart, Penny Lancaster, Geri Horner, Sally Wood, Holly Willoughby, Dan Baldwin and Christian Horner attended a Prince’s Trust event on Thursday

Geri went for a bridal inspired look in a white strapless gown with a daring thigh-split, paired with a matching capped sleeve jacket.

The Spice Girl added extra glamour with a string of pearls, with her auburn tresses swept into an elegant chignon.

Model Penny opted for a metallic gold ballgown with a high-neck which flattered her statuesque figure, teamed with a furry black jacket.

Sally, who is married to Rolling Stones rocker Ronnie, looked sensational in a gold bejewelled ballgown with an elegant tiered lace skirt as she posed next to Holly.

Line-up: Geri, 47, went for a bridal inspired look in a white strapless gown paired with a matching capped sleeve jacket as she posed with Rod and husband Christian

Line-up: Geri, 47, went for a bridal inspired look in a white strapless gown paired with a matching capped sleeve jacket as she posed with Rod and husband Christian

Regal: The Spice Girl added extra glamour with a string of pearls, with her auburn tresses swept into an elegant chignon

Regal: The Spice Girl added extra glamour with a string of pearls, with her auburn tresses swept into an elegant chignon

 Her brunette locks were pulled into a coiffed updo with curly strands framing her immaculately made-up face.

Rod, Redbull racing guru Christian, and TV producer Dan opted for classic black suits as they joined the group.

Christian and Rod later joined forces for a fun video, as they danced together with Rod appearing to plant a kiss on the hunk in the snaps captioned: ‘Do ya think I’m sexy?’ 

The charity was founded by the Prince of Wales in 1976 and helps vulnerable young people aged 11-30, who are unemployed or struggling at school, to transform their lives.  

Fun: Christian and Rod later joined forces for a fun video, as they danced together

Fun: Christian and Rod later joined forces for a fun video, as they danced together

Fun: Christian and Rod later joined forces for a fun video, as they danced together

Pals: Rod and Christian looked dapper as they danced at the star-studded soiree

Pals: Rod and Christian looked dapper as they danced at the star-studded soiree

Banter: Rod looked in good spirits as he danced for the hilarious video filmed by Geri

Banter: Rod looked in good spirits as he danced for the hilarious video filmed by Geri

Banter: Rod looked in good spirits as he danced for the hilarious video filmed by Geri

Holly’s appearance comes after she suffered a hilarious faux pas during Wednesday’s episode of This Morning, after she covered her teeth in chocolate during a baking segment.   

The TV presenter was making some Valentine’s Day treats with co-host Phillip Schofield and chocolatier Paul A Young when the mishap occurred.

Holly appeared to be in a playful mood as she smothered her teeth with the sweet sauce, before flashing a huge grin for the camera.

The star was excited about the smell of chocolate in the studio as they prepared to make chocolate pinatas as a treat ahead of the romantic occasion.

While Pal whisked a bowl of chocolate, Holly picked up a spoon as she asked to try some, saying: ‘I just want a little bit’.

However when trying the chocolate, Holly appeared to misjudge where her mouth was and smothered her teeth with the chocolate-covered spoon. 

Her co-host Phillip Schofield gasped at the gaffe before covering his mouth in shock, quipping: ‘Straight down the dentist then?’

Holly made the best of an embarrassing studio, and rather than being left red-faced she poked fun at the situation and covered her face with more chocolate.  

She then pulled a series of seductive poses as she laughed: ‘Happy Valentine’s Day!’

Wow: Holly looked effortlessly chic in her pink and black asymmetric gown

Wow: Holly looked effortlessly chic in her pink and black asymmetric gown